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Research Turns Swine Manure into Biocrude Products

schideman1Researchers at the University of Illinois have come up with a way to turn swine manure into a biocrude oil, as well as growing algae biomass, capturing carbon, purifying wastewater and recycling nutrients. This news release from the school says Yuanhui Zhang and Lance Schideman, both professors in the Department of Agricultural and Biological Engineering, have combined their years of research for the innovative development.

“We first convert swine manure into crude oil in a hydrothermal liquefaction reactor,” Schideman said. “There is a very strong wastewater that comes off that process. It contains nutrients that can be used to grow algae that simultaneously clean the water. Lately, we’ve added low-cost, bioregenerable adsorbents into the system that allow us to grow additional bacterial biomass and further improve effluent water quality.

“Our recent research, a combination of experimental work and some computer modeling, has shown that we can reuse the nutrients multiple times and thus amplify biofuel production from waste feedstocks,” he explained. “If we start with a particular waste stream that has one ton of volatile solids in it, we might be able to produce three, five or even ten tons of algal and bacterial biomass. This new biomass is then recycled back into the biofuel production process,” he continued. “It can also clean the water with the goal of making it suitable for environmental discharge or reuse in some other application. So we get more bioenergy and more clean water resources – both good things in the long run.”

The biocrude oil has higher oxygen and higher nitrogen content than traditional petroleum, but lower sulfur content. The researchers see the process helping bridge the gap between the smaller refineries and petroleum’s requirements of having refineries that process hundreds of thousands of barrels of material each day.

The biocrude oil is being tested as an asphaltic binder in a piece of pavement leading to Six Flags St. Louis.

LS9 Expands Demonstration Facility

LS9 has announced plans to expand its operations at their Okeechobee, Florida demonstration facility with a successful customer trial. The Florida facility was initially designed, and has been used, to scale-up LS9′s fermentation technology and generate large commercial samples for testing and product qualification by key partners and prospective customers. Since the company’s initial run at 135,000 liter scale in the third quarter of last year, LS9 has made several additional fatty alcohol runs of this size as well as smaller production runs of fatty acid methyl esters (biodiesel).

LS9In addition, LS9 has successfully completed a pilot production run at its Florida plant for another advanced bioproducts company, Cobalt Technologies. According to LS9, fermentation scale-up is an expensive proposition and requires the proper facilities and expertise to make an effective run. The need to run trials is also intermittent so it is not cost-effective for many companies in the industry to make the investment in a larger plant.

LS9 says its Florida demonstration plant was designed to manage a multitude of processes, and with this successful customer run, they have proven they can leverage their state-of-the-art facility and the expertise of its operations staff to work with partners to commercialize renewable products. Given the success of the initial production run, says LS9, Cobalt is considering future work at LS9′s Florida facility.

“The capability to transition from the lab to 135,000 liter scale is a key milestone on our road to commercial success, and we know we are not alone in this requirement,” said Tjerk de Ruiter, President and Chief Executive Officer of LS9. “Our ability to support other companies’ technology scale-up activities is not only an example of the flexibility and the capabilities of our team, it is also an excellent example of how, as an industry, we can work together to make a renewable future a reality. This new revenue source, together with a recent $6 million investment from our current investors, positions LS9 to enter into new partnerships with our technology and advance our own products.”

New Plant-Based Cellulase Enzyme

Iowa Corn Field in Aug Photo Joanna SchroederInfinite Enzymes has launched IE-CBHI, a single activity, plant-based cellulase enzyme. The enzyme is available for research and development projects through Sigma-Aldrich Corporation.

The global industrial enzymes market is projected to reach 3.74 billion by 2015, not including many emerging applications in advanced biofuels and biobased products. Enzymes are a critical role in converting cellulose and hemicellulose in biomass to sugars, which becomes the foundation to produce biofuels, biochemicals or biomaterials.

According to Infinite Enzymes, their technology produces enzymes in a lower value part of the corn kernel thereby creating a new sustainable market for corn processing by-products.  The company says their technology lowers the cost of sugar production needed for developing low-cost biobased plastics and advanced biofuels.

Recently, Infinite Enzymes received a $450,000 Small Business Innovation Research (SBIR) Phase II grant from the U.S. Department of Agriculture to advance its enzyme development technology.

USDA Supports Sustainable Bioenergy Production

The United States Department of Agriculture (USDA) has awarded $10 million in research grants to help develop production of bioenergy and biobased products. Ag Secretary Tom Vilsack made the announcement while visiting Michigan State University, one of the grant winners.

Ford Concept Car with Biobased materialsWhile there, Vilsack mentioned the growth potential of biobased products as detailed in a recent study by Iowa State University (funded by USDA) that found that while biobased products in automobile manufacturing is increasing, there are still many parts that can be replaced with biobased materials.

“USDA and President Obama are committed to producing clean energy right here at home, to not only break our dependence on foreign oil, but also boost rural economies,” said Vilsack. “These projects will give us the scientific information needed to support biofuel production and create co-products that will enhance the overall value of a biobased economy. Today, with a strong and diversified U.S. agricultural sector, the American automobile industry has a greater incentive for expanding use of biobased products while supporting good-paying jobs here in the United States.”

USDA’s National Institute of Food and Agriculture (NIFA) awarded the grants through the Agriculture and Food Research Initiative (AFRI). AFRI’s sustainable bioenergy challenge area targets the development of regional systems for the sustainable production of bioenergy and biobased products that: contribute significantly to reducing dependence on foreign oil; have net positive social, environmental, and rural economic impacts; and are compatible with existing agricultural systems.

Projects were awarded in four areas: 1) policy options for and impacts on regional biofuels production systems, 2) impacts of regional bioenergy feedstock production systems on wildlife and pollinators, 3) socioeconomic impacts of biofuels on rural communities, and 4) environmental implications of direct and indirect land use change. Click here to view a full list of the winners.

Dyadic Receives 12th Patent

Dyadic International has received its 12th patent, U.S. Patent No. 8,304,212 entitled “Methods and compositions for degradation of lignocellulosic material”. The patent covers methods and compositions for using enzymes mixtures to convert plant biomass into fermentable sugars for the production of various products. The patent also covers novel combinations of enzymes including those that provide a synergistic release of sugars from plant biomass.

“In developing and selling industrial enzymes, our customers and partners not only benefit from Dyadic’s patented C1 platform technology but also from Dyadic’s fungal strains and technologies based on the Trichoderma fungal organism,” said Dyadic’s President and CEO, Mark Emalfarb. “Dyadic uses these strains to produce specialty enzymes that can be used for a variety of applications in such fields as animal health and nutrition, biofuels and bio-based chemicals. As with our growing portfolio of patents covering the C1 technology, this patent will provide Dyadic, its customers and licensees with additional protection for our Trichoderma-based enzyme mixtures.”

The patent also specifically describes methods of increasing the yield of fermentable sugars from fermentation of dried distillers grains (DDGs) using enzyme mixtures comprising glucoamylase, beta-glucosidase and alpha-arabinofuranosidase. More specifically, it specifically covers Trichoderma-based enzyme mixtures, which significantly and unexpectedly increase the yield of fermentable sugars from DDGs. DDGs are obtained after the fermentation of the starch derived from a number of grains including corn, wheat, barley, oats, rice, and rye and are typically used for animal feed. DDGs are also a byproduct of ethanol production which creates synergies in using enzymes for both biofuels and animal feed applications.

SG Biofuels Breakthrough

SG Biofuels has expanded it global network of hybrid trial and agronomic research sites with the addition of eight new JMAX Knowledge Centers located in Brazil, Guatemala and India. The company is also expanding it production facility in Guatemala. Current trials are underway in San Diego, California. The company focuses on the the production of Jatropha for use in biofuels, biochemicals and biomaterials.

According to a company statement SG Biofuels’ hybrids are performing better compared to commercial varieties across multiple geographies in terms of plant vigor, health, flowering consistency, stress tolerance and yield. The success validates the ability to produce crude Jatropha oil for less than $99 per barrel in a range of growing conditions.

“The performance of our hybrids in multiple geographies not only validates the strength of our genetics, but our ability to deploy profitable energy crop projects around the world,” said Kirk Haney, president and chief executive officer. “Through our network of JMax Knowledge Centers, we are developing the highest performing hybrids of Jatropha while establishing best agronomic and production practices for deploying those hybrids at commercial scale.”

According to the company, JMax Knowledge Centers are professionally managed trials using experimental design and statistical analysis to evaluate hundreds of hybrids in a range of environmental and agronomic conditions. The centers serve as outdoor classrooms where SGB agronomists and technical teams conduct training and field tours with customers and growers, develop localized agronomic studies and recommendations and develop high performing Jatropha hybrids for commercial deployment. SGB’s hybrids have been developed following five years of research, drawing from a diverse germplasm library including more than 12,000 unique genotypes.

Biodico & Navy Sign Advanced Biofuels Contract

Biodico has signed an agreement with the U.S. Navy for the development and evaluation of advanced biofuels and bioenergy. The goal is to jointly develop renewable fuel and energy technologies that are appropriate for use at U.S. Naval and Department Of Defense (DOD) facilities worldwide. The co-project is supported, in part, by grants from the California Energy Commission.

The collaboration between the Navy and Biodico will optimize the operation of sustainable biorefineries producing renewable petroleum diesel equivalent liquid fuels, bio-based products and energy using renewable resources. The goal is to lower the per gallon cost of production of the alternative energy source and also to push the advanced technology into the marketplace for commercial scale production.

Biodico’s President and Founder, Russell Teall, said, “As part of this agreement we are building a sustainable biorefinery at Naval Base Ventura County that will produce biofuel and bioenergy at prices competitive with unsubsidized conventional fuel and power. The facility is privately funded, with some of the innovations supported by grants from the California Energy Commission. Sen. Pavley’s landmark initiatives have helped make this project possible.”

Through on-site production of liquid biofuels, biobased products and alternative energy, the Navy can get closer to reaching its goal of reducing its dependence on petroleum by 50 percent by 2020. This, in turn, will provide the Navy access to secure forms of energy. Work under the new contract will include a range of technologies including but not limited to transesterification, gasification, gas to liquids, hydrogenation, anaerobic digestion, catalysis, and the production and processing of feedstocks and co-products.

“This announcement is an exciting outcome of the collaboration between Biodico, the Navy and the California Energy Commission,” said California State Senator Fran Pavley (D-Agoura Hills). “This work is a direct result of California’s commitment to reduce our dependence on foreign oil. The collaboration between Biodico, the Navy and the California Energy Commission will enhance our national security, provide new jobs and improve the environment. It will demonstrate and commercialize advanced biofuel and bioenergy technologies that will be utilized throughout the world. The integration of sustainable agriculture with renewable combined heat and power produced on-site will produce inexpensive advanced biofuels.”

Gevo To Refine Biobutanol Plant

In May of 2012, Gevo, Inc. announced the start-up of its bio-isobutanol plant in Luverne, Minnesota. Since then, the company says it has both produced and shipped commercial quality product in railcars for customers. One thing the company has learned is what works well and what needs to be tweaked. So the company has switched the plant to ethanol production while it refines its bio-isobutanol technology.

“To date, we have proven we can produce bio-isobutanol, and do it on a commercial scale – years ahead of the competition,” said CEO Patrick Gruber, Ph.D. “This start-up is very typical of other start-ups we have done: you have to learn a lot in a very short period of time, both what works well and what needs to be adjusted. Early indications are that, while we are making significant progress towards economic production levels, we will not achieve our desired year-end run rate – instead we would expect to achieve that during 2013.”

“While we have made significant progress towards economic production levels, we have decided to optimize certain specific parts of our technology to further enhance bio-isobutanol production rates,” continued Gruber. He said that it does not make business sense to implement adjustments while having the plant in productions. So their strategy is to switch to ethanol production while the technology is refined.

Gevo has agreements in place with Sasol, Total, VP Racing Fuels, Mansfield Oil, and Land O’Lakes Purina. While the company is currently producing fuel for the transportation market, the company is also developing opportunities in the jet, marine and small engine markets as well as looking at the production of bio-isobutanol for biochemicals and biomaterials.

“In five short years, we have gone from start-up to commercial-scale production at the world’s first commercial bio-isobutanol production facility. Production start-ups are never easy, but we are years ahead of our competition and well on our way to realizing economic production levels during 2013,” Gruber concluded.

Algae Facility Partners with ReVenture Park

Renewed World Energies (RWE) has agreed to enter into a partnership with ReVenture Park in Charlotte, North Carolina to develop an algae-to-fuel pilot plant. The Eco-Industrial Park caters to clean energy businesses and will work with RWE to expand its technology from pilot scale to commercial scale. The company is developing different strains of algae that will be utilized to create biofuels as well as health supplements. The pilot facility is expected to be operational September 30, 2012.

There are numerous species of algae and each one has its own unique characteristics. One goal of researchers is to identify and develop strains that are best fits for certain uses, such as to produce jet fuel or for use as a replacement for oil in cosmetics, food and fertilizer. RWE’s system produces algae oil and algae cake, which can be fed as a food supplement to livestock or to make fish feed.

RWE President Richard Armstrong founded his company in South Carolina but chose North Carolina to take it to the next level. “We were attracted to the eco-industrial synergies at ReVenture Park. North Carolina also seems to be more attuned to the renewable fuels, and offers multiple benefits for showcasing new technology.”

ReVenture Park took advantage of nearly 700 acres of abandoned land that was a former textile dye-manufactured site. It is now being transformed into an Eco-Industrial Park focused on research and development of clean technology.

“We are pleased to have struck a deal to have RWE move a facility to ReVenture,” said Tom McKittrick, President Forsite Development. “RWE was attracted to the sites extensive existing infrastructure which then can utilize and there are multiple opportunities for us to collaborate.”

Getting More Products From Soybeans

During the 244th National Meeting & Exposition of the American Chemical Society a new integrated soybean biorefinery was revealed. The technology is designed to create a wider portfolio of products from soybeans.

“Mention soybeans to most people, and they immediately think of the oil,” said Ramani Narayan, Michigan State (MSU) University Distinguished Professor, who reported on the new biorefinery technology. “Soybean oil is the world’s most widely used edible oil. It’s in some margarines, shortenings, mayonnaise, salad dressings, frozen foods, baked goods and many other items. But soybeans are about more than oil. Soybeans are nuggets of green gold that can be a treasure trove of ingredients for other products, and our new biorefinery provides a glimpse of that potential.”

The biorefinery is a fairly new product, often times it is associated with second generation feedstocks such as corn stover, algae and agricultural waste that can produce biofuels, biomaterials and biochemicals. Until now, the mention of soybeans in this emerging environment was rare.

Narayan aid that soybeans pack similar potential as corn as a feedstock but until now, soybean processing facilities have typically focused on producing oils and meal for livestock feed. Switching to the biorefinery concept, the soybean can be transformed into a much wider array of valuable materials. For example, components of a soybean could be turned into polyurethanes, including rigid foam insulation, flexible foams for packaging, as well as coatings, adhesives and elastomers.

The soybean meal could be further processed to yield components used in polyester plastics for fabrics, ropes, car tires, plastic bottles, and LCD screens as well as used in Nylon and Kevlar for bulletproof vests and fire-resistant Nomex. Not enough? Soybeans could also be broken down and built back up as as an ingredient is formaldehyde, a toxic chemical used in a range of products from paint to clothing to children’s toys. And the list goes on.

“The biorefinery can utilize essentially every component of the soybean in the production of bio-based ingredients for high-value products,” Narayan added. “It makes sense from a sustainability standpoint, in which we strive to reduce our dependence on petroleum as a feedstock. It also benefits the soybean farmers and raises the value of the local economy.”

LS9 Announces Grand Opening Ceremony

The Florida Opportunity Fund’s (FOF) Clean Energy Investment Program has awarded funds to LS9 to aid in the company’s grand opening plans for its biorefinery in Okeechobee, Florida. Earlier this year, FOF awarded LS9 $4.5 million to help fund the retrofit of their demonstration facility that when in operation will produce biodiesel and renewable chemical products. With the retrofit complete, the company will begin scaling up its technology to commercial production levels.

LS9 will be hosting a grand opening event on Tuesday, June 12th at its facility to showcase its technology and products. U.S. Congressman Tom Rooney (R-Fla.) will be on hand along with other notable persons and company representatives. The company anticipates production will begin this summer.

“LS9 has been working diligently to complete the retrofit of our Okeechobee facility, and we greatly appreciate the support of the Florida Opportunity Fund on this project,” said Ed Dineen, LS9 President and CEO. “We are honored to have the support of Congressman Rooney for our Grand Opening event and believe this facility can be a magnet for attracting other advanced agricultural and bio-product technologies to the state. Our Florida location is ideal as it allows for prime access to the feedstocks required to produce our renewable products.”

The company plans on producing biodiesel as its first product. In addition, the demonstration biorefinery will produce commercial samples for testing and product qualification by key partners and potential customers. The plant will also test and optimize new process conditions – all in preparation for commercial scale production.

Jennifer Dunham with Florida First Partners, the manager of the FOF Clean Energy Investment Program added, “The State of Florida recognizes the need for adoption of renewable energy products and remains committed to supporting companies, such as LS9, striving to produce these technologies.”

Algasol Renewables Partners with OriginOil

Algasol Renewables, based in Palma De Mallorca, Spain, has agreed to work with OriginOil on the development of an integrated algae growth and harvesting system. Algasol has a patented technology for low-cost cultivation of micro algae for biofuels and byproducts. By bundling their products, the companies hope to achieve new levels of cost and performance in micro algae cultivation for biofuels and bioproducts.

NASA and Lawrence Berkley are working with Algasol to refine their technology, and also collaborates and maintains a close relationship with Arizona State University’s Center for Algae Technology and Innovation.

Miguel Verhein, executive director of Algasol Renewables said, “With customer demand for an integrated algae production process rising, we need to offer our customers a means of harvesting as well. We plan to recommend OriginOil’s field-proven chemical-free, high flow and low-energy harvesting system, and once available, the integrated biocrude system they are developing with the Department of Energy.”

Algasol’s floating bags or photobioreactors (PBRs) can operate in the ocean or in land-based salt water ponds, and have received a patent in 70 countries. Because they float, Algasol believes their PBRs achieve optimal light exposure with strong productivity results and avoid the high temperature and excess salinity often encountered in solar growth systems.

“Algasol’s patented system focuses on how to grow algae in floating bags, and their testing has indicated this can be much more efficient than other cultivation methods,” said Riggs Eckelberry, OriginOil’s CEO. “Now with NASA and Lawrence Berkley working with Algasol, we are excited and eager to contribute our own breakthrough harvesting system to help us collectively achieve a cost breakthrough in the race to compete with petroleum.”

EdeniQ Secures $30M in Bio Funding

Despite the sluggish economy, select advanced bioproducts companies are still receiving funding. EdeniQ has announced that they have secured over $30 million in capital in the form of an equity investment and debt facility. The funds will be used to continue development of its technology to convert sugars to biomaterials such as biochemicals and biofuels. The investment was led by current investors along with a new investor, Flint Hills Resources Renewables.

According to EdeniQ, its technology increases yield and output at existing ethanol plants and provides a pathway to move into cellulosic feedstocks. The Cellunator mills a variety of biomass into small, uniform pieces of feedstock that using Pathway enzymes to break down the materials can be converted at low cost to sugars. The company’s technology can be added as a bolt-on to existing ethanol facilities or integrated into new cellulosic ethanol processing plants.

“The market is eager for innovation that can scale from today’s ethanol technology to tomorrow’s resource requirements by creating the lowest-cost route to cellulosic sugars and subsequent high-value products,” said Brian Thome, President and CEO, EdeniQ. “The investments by these prestigious organizations allow EdeniQ to continue our strategy of taking advantage of the existing infrastructure in place across the country and providing a proven pathway to increased sugar yield.“

Flint Hill Resources has four ethanol plants operating in Iowa. Jeremy Bezdek, the company’s managing director of innovation said they invested in EdeniQ because, “EdeniQ’s proprietary technologies provide significant value for the dry-mill ethanol producer in today’s marketplace. Our investment in EdeniQ is another step in our vision to enhance the competitive advantage of our ethanol production facilities.”

Driving The Bioeconomy Highway

The National Bioeconomy Blueprint was recently released by the Obama Administration.  The report outlines the steps that agencies need to take to drive the bioeconomy highway.  The Administration recognized the growing sector has a priority due to its potential for growth and job creation.  The bioeconomy will also help drive new sources of bioenergy, improve the agricultural industry, change the face of manufacturing and address key environmental issues, among other benefits.

America’s economy is slowing transforming to a biobased economy.  ”Home-grown” bioproducts already developed include food, feed and fiber as well as chemical substitutes for petroleum-based products; yet the industry has barely emerged. Research is critical to the future of the industry, but it is also important, according to the report, to equip the workforce with the education, training and skills they need to have thriving careers in the sector.

Another step that needs to be taken is to reduce the troublesome regulatory barriers in order to accelerate the advancement of bioinventions and bring them to market.  There are concerns, both health and ethical, that are a result of work being done with biological systems.

The Bioeconomy Blueprint outlines ”five strategic imperatives” for a bioeconomy with the potential to generate new markets and economic growth:

  • Support R&D investments that will provide the foundation for the future bioeconomy.
  • Facilitate the transition of bioinventions from research lab to market, including an increased focus on translational and regulatory sciences.
  • Develop and reform regulations to reduce barriers, increase the speed and predictability of regulatory processes, and reduce costs while protecting human and environmental health.
  • Update training programs and align academic institution incentives with student training for national workforce needs.
  • Identify and support opportunities for the development of public-private partnerships and precompetitive collaborations—where competitors pool resources, knowledge, and expertise to learn from successes and failures.

In conclusion, the Blueprint calls upon Federal agencies to accelerate their support of the bioeconomy sector for the benefit of the country.

Virdia Opens New Pilot Facility

A new cellulosic demonstration facility has opened in Danville, Virginia. Virdia, a company focused on developing cellulosic sugars,  located the facility on the campus for the Institute for Advanced Learning and Research (IALR). The facility will prove out Virdia’s CASE process in pilot scale and the resulting  cellulosic sugars and lignin will be designed for use in commercial applications.

Philippe Lavielle, Virdia CEO said, “Siting our technology center and our demonstration facility in Virginia is the next key step towards commercial production for us. Virdia’s products are cost-competitive, and are setting new standards for industrial uses of cellulosic sugars and lignin.”

Lavielle also said that the company looks forward to demonstrating the technology on a larger scale, and when they are ready, plan on locating the larger facility near sustainable sources of biomass.  The CASE process converts biomass to fermentable sugars and lignin. The resulting sugars can be used to produce renewable chemicals, materials, nutritional additives for the feed industry and renewable fuels. The company is currently working with Virent who is using the sugars to produce drop-in jet fuels.

The company held a ribbon cutting ceremony on April 25th.  ”Virdia is making huge strides in the emerging bioeconomy, and I am pleased the company has decided to site its new technology center in Virginia,” said Bob McDonnell, the Governor of Virginia. “The development of sustainable and clean sources of energy is a necessary component of our all the above energy strategy, and Virginia is proud to welcome Virdia to the state in pursuance of cleaner energy, scientific innovation and economic stimulus.”